5,7-Dihydroxy-2-(3-hydroxy-4,5-dimethoxyphenyl)-6-methoxy-4H-chromen-4-one

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Crystal structure of 2-(4-tert-butyl­phen­yl)-3-hydroxy-4H-chromen-4-one

Yellow-green fluorescent crystals of the title compound, C19H18O3, were obtained by the reaction of hy-droxy-aceto-phenone and 4-tert-butyl-benzaldehyde with hydrogen peroxide as oxidant. The plane of the benzene ring is slightly twisted to the mean plane of the 4H-chromene-4-one moiety (r.m.s. deviation = 0.0191 Å) by 10.53 (8)°. In the crystal, mol-ecules are linked by pairs of O-H⋯O hydrogen...

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3-Hy­droxy-2-(4-hy­droxy­phen­yl)-4H-chromen-4-one

In the title compound, C(15)H(10)O(4), the benzene ring is twisted at an angle of 20.7 (1)° relative to the 4H-chromene skeleton. In the crystal, adjacent mol-ecules are linked via a network of O-H⋯O and C-H⋯O hydrogen bonds. The mean planes of adjacent 4H-chromene moieties are parallel or oriented at an angle of 20.9 (1)° in the crystal structure.

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3-(3-Nitro­benz­yl)-4H-chromen-4-one

In the title compound, C16H11NO4, the dihedral angle between the 10-membered coplanar chromone ring system and the benzene ring is 77.83 (3)°. In the crystal, weak C-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network.

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3-(4-Nitro­benz­yl)-4H-chromen-4-one

In the title compound, C16H11NO4, the dihedral angle between the ten-membered chromen-4-one ring system (r.m.s. deviation = 0.0095 Å) and the benzene ring is 86.16 (5)°. In the crystal, mol-ecules are linked into a three-dimensional network by weak C-H⋯O hydrogen bonds. The crystal studied was a non-merohedral twin, with the minor twin component refining to 0.093 (1).

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2-(4-Fluoro­phen­yl)-3-hy­droxy-4H-chromen-4-one

In the crystal structure of the title compound, C(15)H(9)FO(3), inversely oriented mol-ecules form inversion dimers through pairs of O-H⋯O hydrogen bonds. The benzene ring is twisted at an angle of 12.0 (1)° relative to the 4H-chromene skeleton of the mol-ecule. Adjacent 4H-chromene units are parallel in a given column or oriented at an angle of 50.0 (1)° in neighboring, inversely oriented, col...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2013

ISSN: 1600-5368

DOI: 10.1107/s1600536813007381